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Unimolecular Reactions: A Concise Introduction

Paperback / softback

Main Details

Title Unimolecular Reactions: A Concise Introduction
Authors and Contributors      By (author) Wendell Forst
Physical Properties
Format:Paperback / softback
Pages:332
Dimensions(mm): Height 248,Width 175
Category/GenreAtomic and molecular physics
Physical chemistry
ISBN/Barcode 9780521529228
ClassificationsDewey:541.39 541.39
Audience
Professional & Vocational
Tertiary Education (US: College)
Illustrations Worked examples or Exercises; 58 Line drawings, unspecified

Publishing Details

Publisher Cambridge University Press
Imprint Cambridge University Press
Publication Date 25 September 2003
Publication Country United Kingdom

Description

The statistical theory of unimolecular reactions is now universally known as RRKM theory. This textbook covers the basics necessary for the understanding of RRKM theory in its original and variational, phase-space and angular momentum-conserved incarnations. After a review of the Kassel quantum model and the theory of Slater, the specific-energy RRKM rate constant k(E) is derived. The argument is then extended to the angular momentum-dependent rate constant k(E,J), to non-classical effects (tunneling and non-adiabatic transition), and the general problem of angular momentum conservation. A long chapter is devoted to the counting of quantum states. The chapter on thermal systems discusses both analytical and numerical solutions and is later extended to include the variational approach and discussion of exit channel effects. Containing many problem sets and solutions, the book is targeted at graduate and advanced undergraduate students studying chemical dynamics, chemical kinetics and theoretical chemistry.

Author Biography

Affiliated with the Laboratoire de Physicochimie Moleculaire, Universite Bordeaux I, Talence, France

Reviews

'The striking element of this book is its elegant, yet simple, presentation of the unimolecular reactions ... Students will appreciate the readability and clarity of the presentation of this book. This will surely become the modern day "classic".' ChemPhysChem